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• W2069344564 abstract "Non-resonant anti-Stokes Raman probing of vibrational excitations following ultrafast (400 fs in methanol) internal conversion of para-nitroaniline is demonstrated. Immediately after this process an anti-Stokes signal blue shifted by 1290 cm−1 with respect to the probe laser pulse at 815 nm appears. The signal which is due to the NO2 stretch vibration moves to an anti-Stokes shift of 1315 cm−1 corresponding to the Stokes position of this vibration in 1 ps. The decay of this signal is slower and occurs within 3 ps. Possible origins of the strong initial red-shift of the anti-Stokes line are discussed." @default.
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• W2069344564 date "2002-09-01" @default.
• W2069344564 modified "2023-10-10" @default.
• W2069344564 title "Cooling of hot para-nitroaniline probed by non-resonant Raman scattering" @default.
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• W2069344564 doi "https://doi.org/10.1016/s0009-2614(02)01182-x" @default.
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