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• W2069354964 endingPage "107" @default.
• W2069354964 startingPage "93" @default.
• W2069354964 abstract "Abstract Coordination compounds formed by the interaction of uranyl nitrate with several potentially bidentate ligands — 1,10-phenanthroline, 2,2′-bipyridyl, 2,2′-bipyridyl-N,N′-dioxide, 2,2′-bipyridylamine, 4,4′-bipyridyl, 4,4′-bipyridyl-N,N′-dioxide, methylpyrazine, quinoxaline, 2,3-dimethylquinoxaline, hexamethylene-tetramine, 1,3-di(4-pyridyl)propane, 2-methylbenzothiazole and nicotinic acid — have been prepared. Stoichiometries of the complexes have been established by metal, carbon, hydrogen and nitrogen analyses. The complexes isolated in the solid state have been characterized by i.r. spectroscopy down to 200 om−1 to elucidate the metal-ligand and metal-nitrate bonding modes. It is shown that some of the ligands though with two donor sites nevertheless act only as monodentate ligands. Some of the ligands possessing more than two sites of coordination, however, act as bidentate ligands only. The nitrate groups are also coordinated and act as bidentate chelating ligands in all the complexes studied. Tentative coordination numbers and stereochemical environments around uranium(VI) are discussed in each case." @default.
• W2069354964 created "2016-06-24" @default.
• W2069354964 creator A5084669882 @default.
• W2069354964 date "1985-02-01" @default.
• W2069354964 modified "2023-09-27" @default.
• W2069354964 title "Synthesis and Structural Information on Uranyl Nitrate Complexes with Some Bidentate Ligands" @default.
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• W2069354964 doi "https://doi.org/10.1080/00945718508059369" @default.
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