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• W2069358466 abstract "Abstract Ternary complexes of formulae [Cu(dipeptide)(nucl)2]Cl2·xH2O with dipeptides glycyl-glycine (Gly-Gly), glycyl- l -alanine (gly-Ala), glycyl- l -valine (Gly-Val), glycyl- l -leucine (Gly-Leu) and nucl inosine (ino)_and guanosine (guo) were isolated from a water : ethanol (2 : 1) solution and characterized with elemental analysis, conductivity measurements, IR, electronic and ESR spectra. At low pH values ( 4 the dipeptides coordinate through the (—NH2) terminal and the deprotonated amide (—N−) groups. The pKa values for these deprotonations were estimated with electronic spectra and increase with the increase of the side chain of the dipeptides, due to steric reasons. At higher pH values one nucleoside molecule is liberated and replaced by the terminal deprotonated carboxylate group of the dipeptides. The pK values for these transformations were calculated with ESR spectra and follow the same trend as for the deprotonation constants and for the same reason." @default.
• W2069358466 created "2016-06-24" @default.
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• W2069358466 date "1995-05-01" @default.
• W2069358466 modified "2023-09-27" @default.
• W2069358466 title "Ternary complexes of copper(II) containing inosine (Ino), guanosine (Guo) and the dipeptides, GLY-GLY, GLY-l-ALA, GLY-l-VAL and GLY-l-LEU" @default.
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• W2069358466 doi "https://doi.org/10.1016/0277-5387(94)00381-n" @default.
• W2069358466 hasPublicationYear "1995" @default.
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