Matches in SemOpenAlex for { <https://semopenalex.org/work/W2069366158> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2069366158 endingPage "2709" @default.
- W2069366158 startingPage "2703" @default.
- W2069366158 abstract "Diphenyl ether (Ia) was converted to o-phenylphenol (IIa, 20·4%), p-phenylphenol (IIIa, 12·7%) and a small amount of phenol (IVa, ca. 0·4%) by irradiation with UV light in various solvents. p,p′-Ditolyl ether (Ib) was similarly converted to 2-(p-tolyl)-4-methylphenol (IIb, 14%) and p-cresol (IVb, 7%), indicating that the photochemical rearrangement proceeds via CO bond cleavage and recombination of the radical fragments. These reactions are intramolecular and occur via an excited singlet state or via a short-lived triplet. The combined yields of o- and p-rearrangement products were increased from 1 to 18% by an increase of the ratio of ethyl ether to ethanol, implying the facilitation of CO bond fission by the H- bonding of ethanol to diphenyl ether (Ia) or the stabilization of quinoid intermediates (VIII and IX)." @default.
- W2069366158 created "2016-06-24" @default.
- W2069366158 creator A5012763473 @default.
- W2069366158 creator A5020111895 @default.
- W2069366158 creator A5055856861 @default.
- W2069366158 date "1970-01-01" @default.
- W2069366158 modified "2023-09-23" @default.
- W2069366158 title "Photochemical rearrangement of diaryl ethers" @default.
- W2069366158 cites W1967693656 @default.
- W2069366158 cites W1972540683 @default.
- W2069366158 cites W2002214764 @default.
- W2069366158 cites W2006506691 @default.
- W2069366158 cites W2037356075 @default.
- W2069366158 cites W2074214020 @default.
- W2069366158 cites W2086338807 @default.
- W2069366158 cites W2088117496 @default.
- W2069366158 cites W2314200457 @default.
- W2069366158 cites W2315266509 @default.
- W2069366158 cites W2315831492 @default.
- W2069366158 cites W2316270951 @default.
- W2069366158 cites W2318187322 @default.
- W2069366158 cites W2322928231 @default.
- W2069366158 cites W2334673133 @default.
- W2069366158 cites W2607112042 @default.
- W2069366158 doi "https://doi.org/10.1016/s0040-4020(01)92845-5" @default.
- W2069366158 hasPublicationYear "1970" @default.
- W2069366158 type Work @default.
- W2069366158 sameAs 2069366158 @default.
- W2069366158 citedByCount "29" @default.
- W2069366158 countsByYear W20693661582013 @default.
- W2069366158 countsByYear W20693661582016 @default.
- W2069366158 countsByYear W20693661582017 @default.
- W2069366158 countsByYear W20693661582019 @default.
- W2069366158 countsByYear W20693661582020 @default.
- W2069366158 crossrefType "journal-article" @default.
- W2069366158 hasAuthorship W2069366158A5012763473 @default.
- W2069366158 hasAuthorship W2069366158A5020111895 @default.
- W2069366158 hasAuthorship W2069366158A5055856861 @default.
- W2069366158 hasConcept C121332964 @default.
- W2069366158 hasConcept C155647269 @default.
- W2069366158 hasConcept C161790260 @default.
- W2069366158 hasConcept C178790620 @default.
- W2069366158 hasConcept C181500209 @default.
- W2069366158 hasConcept C185544564 @default.
- W2069366158 hasConcept C185592680 @default.
- W2069366158 hasConcept C2777702071 @default.
- W2069366158 hasConcept C2778092639 @default.
- W2069366158 hasConcept C2780161600 @default.
- W2069366158 hasConcept C2780407432 @default.
- W2069366158 hasConcept C3044715 @default.
- W2069366158 hasConcept C33062035 @default.
- W2069366158 hasConcept C71240020 @default.
- W2069366158 hasConcept C75079739 @default.
- W2069366158 hasConcept C75473681 @default.
- W2069366158 hasConceptScore W2069366158C121332964 @default.
- W2069366158 hasConceptScore W2069366158C155647269 @default.
- W2069366158 hasConceptScore W2069366158C161790260 @default.
- W2069366158 hasConceptScore W2069366158C178790620 @default.
- W2069366158 hasConceptScore W2069366158C181500209 @default.
- W2069366158 hasConceptScore W2069366158C185544564 @default.
- W2069366158 hasConceptScore W2069366158C185592680 @default.
- W2069366158 hasConceptScore W2069366158C2777702071 @default.
- W2069366158 hasConceptScore W2069366158C2778092639 @default.
- W2069366158 hasConceptScore W2069366158C2780161600 @default.
- W2069366158 hasConceptScore W2069366158C2780407432 @default.
- W2069366158 hasConceptScore W2069366158C3044715 @default.
- W2069366158 hasConceptScore W2069366158C33062035 @default.
- W2069366158 hasConceptScore W2069366158C71240020 @default.
- W2069366158 hasConceptScore W2069366158C75079739 @default.
- W2069366158 hasConceptScore W2069366158C75473681 @default.
- W2069366158 hasIssue "11" @default.
- W2069366158 hasLocation W20693661581 @default.
- W2069366158 hasOpenAccess W2069366158 @default.
- W2069366158 hasPrimaryLocation W20693661581 @default.
- W2069366158 hasRelatedWork W1485742733 @default.
- W2069366158 hasRelatedWork W1854593855 @default.
- W2069366158 hasRelatedWork W1979869988 @default.
- W2069366158 hasRelatedWork W2001650568 @default.
- W2069366158 hasRelatedWork W2009614525 @default.
- W2069366158 hasRelatedWork W2037449140 @default.
- W2069366158 hasRelatedWork W2140163987 @default.
- W2069366158 hasRelatedWork W2606438493 @default.
- W2069366158 hasRelatedWork W2952108123 @default.
- W2069366158 hasRelatedWork W2020257072 @default.
- W2069366158 hasVolume "26" @default.
- W2069366158 isParatext "false" @default.
- W2069366158 isRetracted "false" @default.
- W2069366158 magId "2069366158" @default.
- W2069366158 workType "article" @default.