Matches in SemOpenAlex for { <https://semopenalex.org/work/W2069376545> ?p ?o ?g. }
- W2069376545 endingPage "3409" @default.
- W2069376545 startingPage "3403" @default.
- W2069376545 abstract "Abstract Diazirinone (cyclic N 2 CO) recently identified in solid noble gas matrices and in the gas phase by infrared spectroscopy, has now been trapped at –196 °C as a neat brownish‐yellow solid, and characterized by low‐temperature IR and Raman spectroscopy. Evaporation of the solid yields violet gaseous N 2 CO, which is surprisingly stable in a clean quartz cell. Its decay at room temperature in the dark follows a second‐order rate law ( k 2 = 4.9 × 10 –2 L mol –1 s –1 ) with a half‐life of 30 h at an initial pressure of 5 mbar. The visible absorption spectrum of the gas reveals a structured band with the 0–0 transition at 567 nm (17651 cm –1 ), and its assignment has been made with the aid of theoretical calculations. Cyclic diazirinone that is isolated in solid Ar at 16 K decomposes upon visible light irradiation to yield N 2 and CO, but after being exposed to ArF excimer laser irradiation (193 nm) the N=N bond is cleaved and the open‐chain isomers NOCN, ONCN, and ONNC are formed." @default.
- W2069376545 created "2016-06-24" @default.
- W2069376545 creator A5027671553 @default.
- W2069376545 creator A5031597966 @default.
- W2069376545 creator A5078055232 @default.
- W2069376545 creator A5090310108 @default.
- W2069376545 date "2012-06-15" @default.
- W2069376545 modified "2023-10-17" @default.
- W2069376545 title "Fascinating Diazirinone: A Violet Gas" @default.
- W2069376545 cites W1966995166 @default.
- W2069376545 cites W1993713159 @default.
- W2069376545 cites W1994032845 @default.
- W2069376545 cites W1998885061 @default.
- W2069376545 cites W2002193246 @default.
- W2069376545 cites W2005148229 @default.
- W2069376545 cites W2007135029 @default.
- W2069376545 cites W2012458244 @default.
- W2069376545 cites W2016176982 @default.
- W2069376545 cites W2019240116 @default.
- W2069376545 cites W2023045364 @default.
- W2069376545 cites W2038004144 @default.
- W2069376545 cites W2038793711 @default.
- W2069376545 cites W2039782557 @default.
- W2069376545 cites W2045731477 @default.
- W2069376545 cites W2049257885 @default.
- W2069376545 cites W2049731100 @default.
- W2069376545 cites W2059021837 @default.
- W2069376545 cites W2059697812 @default.
- W2069376545 cites W2066481445 @default.
- W2069376545 cites W2074271730 @default.
- W2069376545 cites W2076931741 @default.
- W2069376545 cites W2082741337 @default.
- W2069376545 cites W2092930273 @default.
- W2069376545 cites W2122685767 @default.
- W2069376545 cites W2122840805 @default.
- W2069376545 cites W2123748317 @default.
- W2069376545 cites W2132835215 @default.
- W2069376545 cites W2153890042 @default.
- W2069376545 cites W2163541245 @default.
- W2069376545 cites W2168542043 @default.
- W2069376545 cites W2170330973 @default.
- W2069376545 cites W2268094461 @default.
- W2069376545 cites W2314433190 @default.
- W2069376545 cites W2329613897 @default.
- W2069376545 cites W4233965423 @default.
- W2069376545 cites W4239761011 @default.
- W2069376545 doi "https://doi.org/10.1002/ejic.201200337" @default.
- W2069376545 hasPublicationYear "2012" @default.
- W2069376545 type Work @default.
- W2069376545 sameAs 2069376545 @default.
- W2069376545 citedByCount "23" @default.
- W2069376545 countsByYear W20693765452012 @default.
- W2069376545 countsByYear W20693765452013 @default.
- W2069376545 countsByYear W20693765452014 @default.
- W2069376545 countsByYear W20693765452015 @default.
- W2069376545 countsByYear W20693765452016 @default.
- W2069376545 countsByYear W20693765452017 @default.
- W2069376545 countsByYear W20693765452021 @default.
- W2069376545 countsByYear W20693765452023 @default.
- W2069376545 crossrefType "journal-article" @default.
- W2069376545 hasAuthorship W2069376545A5027671553 @default.
- W2069376545 hasAuthorship W2069376545A5031597966 @default.
- W2069376545 hasAuthorship W2069376545A5078055232 @default.
- W2069376545 hasAuthorship W2069376545A5090310108 @default.
- W2069376545 hasConcept C104663316 @default.
- W2069376545 hasConcept C111337013 @default.
- W2069376545 hasConcept C113196181 @default.
- W2069376545 hasConcept C119824511 @default.
- W2069376545 hasConcept C120665830 @default.
- W2069376545 hasConcept C121332964 @default.
- W2069376545 hasConcept C121530826 @default.
- W2069376545 hasConcept C125287762 @default.
- W2069376545 hasConcept C134121241 @default.
- W2069376545 hasConcept C153642686 @default.
- W2069376545 hasConcept C158355884 @default.
- W2069376545 hasConcept C178790620 @default.
- W2069376545 hasConcept C185544564 @default.
- W2069376545 hasConcept C185592680 @default.
- W2069376545 hasConcept C191897082 @default.
- W2069376545 hasConcept C192562407 @default.
- W2069376545 hasConcept C24890656 @default.
- W2069376545 hasConcept C2777896788 @default.
- W2069376545 hasConcept C32891209 @default.
- W2069376545 hasConcept C40003534 @default.
- W2069376545 hasConcept C49040817 @default.
- W2069376545 hasConcept C54582936 @default.
- W2069376545 hasConcept C61441594 @default.
- W2069376545 hasConcept C62520636 @default.
- W2069376545 hasConcept C75473681 @default.
- W2069376545 hasConcept C97355855 @default.
- W2069376545 hasConceptScore W2069376545C104663316 @default.
- W2069376545 hasConceptScore W2069376545C111337013 @default.
- W2069376545 hasConceptScore W2069376545C113196181 @default.
- W2069376545 hasConceptScore W2069376545C119824511 @default.
- W2069376545 hasConceptScore W2069376545C120665830 @default.
- W2069376545 hasConceptScore W2069376545C121332964 @default.
- W2069376545 hasConceptScore W2069376545C121530826 @default.
- W2069376545 hasConceptScore W2069376545C125287762 @default.