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• W2069384115 abstract "A wide range of structurally diverse 3,3′-thiopyrrolidonyl spirooxindoles bearing three contiguous stereogenic centers can be smoothly obtained via a domino Michael/cyclization reaction between 3-isothiocyanato oxindoles and 3-methyl-4-nitro-5-alkenyl-isoxazoles with commercially available quinine as the catalyst under mild conditions. The protocol is significantly characterized by high reactivity, a low catalyst loading (1 mol %), and an excellent diastereo- and enantioselectivity (up to >99:1 dr and 98% ee)." @default.
• W2069384115 created "2016-06-24" @default.
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• W2069384115 date "2013-03-01" @default.
• W2069384115 modified "2023-10-07" @default.
• W2069384115 title "Highly Efficient and Stereocontrolled Construction of 3,3′-Pyrrolidonyl Spirooxindoles via Organocatalytic Domino Michael/Cyclization Reaction" @default.
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• W2069384115 doi "https://doi.org/10.1021/ol400183k" @default.
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