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- W2069443049 abstract "A protohaem compound, used for treatment of porphyrias, has been studied to elucidate its state of aggregation. EPR and absorption spectroscopy measurements reveal that 38.3 mM protohaem, dissolved in 40% 1,2-propanediol/10% ethanol/water solution, also containing 153 mM arginine, is partly EPR silent. It exists as high molecular weight aggregates and probably also as mu-oxo-dimers. Dilution in the aqueous alcohol solution dissolves the aggregates first to oligomers and dimers, and finally to monomers (Kdiss = 24 X 10(-6)M). When haem is diluted in 0.9% sodium chloride, a fully monomeric state is not reached even at 1 microM concentration. At 3.5 microM concentration, that used for infusion in patients, the haem is still totally aggregated." @default.
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- W2069443049 date "1987-01-01" @default.
- W2069443049 modified "2023-09-26" @default.
- W2069443049 title "Optical and EPR spectroscopy studies on haem arginate, a new compound used for treatment of porphyria" @default.
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- W2069443049 doi "https://doi.org/10.1016/0009-2797(87)90091-3" @default.
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