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• W2069448871 startingPage "2686" @default.
• W2069448871 abstract "The carbamoyl ferrate Li[Fe{C(O)NiPr2}(CO)4] reacts in diethyl ether with Br2PPh3, I2PPh3, or I2 followed by triphenylphosphine to provide the complexes [Fe(η2-OCNiPr2)X(CO)2(PPh3)] [X = I trans to PPh3 (1a); Br (1b) two isomers], each of which feature dihapto-C,O carbamoyl coordination. The reactions of 1a or 1b with AgBF4 in the presence of CO provide [Fe(η2-OCNiPr2)(CO)3(PPh3)]BF4 (2a·BF4), one carbonyl ligand of which is labile and readily replaced by I-, Br-, or PPh3 to provide 1a, 1b, or [Fe{η2-OCNiPr2}(CO)2(PPh3)2]BF4 (2b·BF4). The reaction of 1a with dppe leads to a separable mixture of the salt [Fe{η2-OCNiPr2}(CO)2(dppe)]I (3·I) and [Fe{η2-OCNiPr2}I(CO)(dppe)] (4). Successive treatment of Li[Fe{C(O)NiPr2}(CO)4] with ClSnPh3 and PPh3 provides the stannyl complex [Fe(η2-OCNiPr2)(SnPh3)(CO)2(PPh3)] (1d). Treating 1d with iodine leads to Sn−Fe rather than Sn−C cleavage and formation of 1a. In all the above transformations the integrity of the dihapto carbamoyl coordination is ultimately retained. The crystal structures of 1d and 2b·PF6 are reported." @default.
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• W2069448871 date "2004-04-22" @default.
• W2069448871 modified "2023-09-27" @default.
• W2069448871 title "Dihapto Carbamoyl (Carboxamide) Complexes of Iron(II)" @default.
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• W2069448871 doi "https://doi.org/10.1021/om0306933" @default.
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