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- W2069451569 abstract "Racemic tetrahydropyran 3 was efficiently synthesised from allylsilane 6 and aldehyde 7 via an intramolecular Sakurai cyclisation. In a single step, the relative configuration of three chiral centres was established. Allylsilane 6 was readily assembled from 1-iodo-1-selenopropene 10, a synthetic equivalent of a propene 1,1-dianion." @default.
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- W2069451569 date "2005-07-01" @default.
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- W2069451569 title "A connective approach to the tetrahydropyran subunit of polycavernoside A via a novel 1,1-dianion equivalent" @default.
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- W2069451569 doi "https://doi.org/10.1016/j.tetlet.2005.05.054" @default.
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