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- W2069457654 abstract "We have examined the reaction of hydantoin (=imidazolidine-2,4-dione) with (formylphenyl)boronic acids, where the addition of a boronic acid group is hoped to increase bioactivities. Addition of (2-formylphenyl)boronic acid to hydantoin gave an unexpected azaborine compound, which presumably arises by initial formation of the (phenylmethylidene)hydantoin, with subsequent loss of H2O to give the cyclized product. Reactions of (3-formylphenyl)- and (4-formylphenyl)boronic acids with hydantoin gave the corresponding [(Z)-phenylmethylidene]hydantoins in good-to-excellent yields. Attempts to use (3-formylthiophen-2-yl)boronic acid gave a product where the boronic acid group has been cleaved." @default.
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- W2069457654 date "2010-06-15" @default.
- W2069457654 modified "2023-09-27" @default.
- W2069457654 title "Reaction of Hydantoin with Boronic Acids" @default.
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- W2069457654 doi "https://doi.org/10.1002/hlca.201000022" @default.
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