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- W2069463719 startingPage "1338" @default.
- W2069463719 abstract "The well-known cumulant-summation formula is applied to the low-temperature calculation of the quantum-mechanical partition functions for many particle systems. The motivation for this method is to be able to deal with many-particle states directly and avoid the usual starting point of independent single-particle states. The test case chosen for this method was the calculation of the canonical partition function and the grand-canonical partition function for the degenerate free-electron gas. The result is that the expected equivalence of the canonical and grand-canonical ensembles is not found at low temperatures. The role of few-particle fluctuations in the grand-canonical ensemble is shown to be extremely important to the thermal properties of the degenerate free-electron gas and in the difference between the ensembles." @default.
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- W2069463719 date "1992-07-15" @default.
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- W2069463719 title "Partition functions for many-particle systems" @default.
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- W2069463719 doi "https://doi.org/10.1103/physrevb.46.1338" @default.
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