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• W2069483134 abstract "Durch Metallierung von cis-Mo(CO)4(PhPH2)2 (1) mit n-Butyl- bzw. Methyllithium erhält man den Lithiumphenylphosphido-Komplex cis-Mo(CO)4(PhPHLi)2 (1a). Dessen Umsetzung mit Chlortrimethylsilan, 1,2-Dichlor-1,1,2,2-tetramethyldisilan, Bis(cyclopentadienyl)titan- bzw. -zirconiumdichlorid liefert die Komplexe Mo(CO)4(PhPHSiMe3)2 (2) bzw. Mo(CO)4(PhPH)2Z (3–5)(Z = Me2SiSiMe2, TiCp2, ZrCp2). Die analoge Reaktionsfolge liefert ausgehend von 2 bzw. Mo(CO)4(PhPHSiMe2SiMe2PPhH) (3) Komplexe des Typs cis-Mo(CO)4(PhPSiMe3)2Z (6–9) (Z = TiCp2, ZrCp2, Me2Si, Me2SiSiMe2) und cis-Mo(CO)4PhP(SiMe2SiMe2)2PhP (10). Die Struktur dieser Verbindungen wird auf der Basis ihrer Kernresonanz- und Infrarotspektren diskutiert. Reactions of Coordinated Ligands, IV. Synthesis of Asymmetrically Substituted Bifunctional Phosphine Ligands in the Coordination Sphere of the Phosphido Complex cis-Mo(CO)4(PhPHLi)2 Metalation of cis-Mo(CO)4(PhPH2)2 (1) with n-butyl- or methyllithium affords the lithium phenylphosphido complex cis-Mo(CO)4(PhPHLi)2 (1a) which with chlorotrimethylsilane, 1,2-dichloro-1,1,2,2-tetramethyldisilane, bis(cyclopentadienyl)titanium or zirconium dichloride gives the complexes cis-Mo(CO)4(PhPHSiMe3)2 (2) or cis-Mo(CO)4(PhPH)2Z (3–5) (Z = Me2SiSiMe2, TiCp2, ZrCp2). The corresponding reaction succession starting with 2 or cis-Mo(CO)4(PhPHSiMe2SiMe2PPhH) (3) yields the complexes cis-Mo(CO)4(PhPSiMe3)2Z (6–9) (Z = TiCp2, ZrCp2, Me2Si, Me2Si–SiMe2) and cis-Mo(CO)4PhP(SiMe2SiMe2)2PhP (10). The structure of these complexes is discussed on the basis of their NMR and IR spectra." @default.
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• W2069483134 title "Reaktionen koordinierter Liganden, IV. Aufbau asymmetrisch substituierter zweizähniger Phosphinliganden in der Koordinationssphäre des Phosphidokomplexes <i>cis</i> ‐Mo(CO) ₄ (PhPHLi) ₂" @default.
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• W2069483134 doi "https://doi.org/10.1002/cber.19771101024" @default.
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