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- W2069499323 abstract "Abstract Experiments were carried out to clarify the mechanism for the extraction of Cr(VI) from sulfate-containing aqueous solutions using tri-n-octylamine (TOA). The results were consistent with a two-step reaction mechanism, initially involving complexation of TOA with bisulfate followed by substitution of bisulfate with bichromate in the complex. Experimental results support the contention that the first step only occurs with bisulfate and not with sulfate, explaining why the extraction decreases rapidly for initial pH values above 2. The equilibrium coefficient for the overall extraction reaction was determined to be 106." @default.
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- W2069499323 date "1994-02-01" @default.
- W2069499323 modified "2023-09-25" @default.
- W2069499323 title "Chemistry of Cr(VI) Solvent Extraction Using Tri-n-octylamine" @default.
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