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- W2069532098 abstract "The first total synthesis of the Lycopodium alkaloid (+)-fastigiatine has been accomplished in 15 steps and 30% overall yield from known compounds. Noteworthy transformations include a convergent fragment coupling via a nucleophilic cyclopropane opening, a highly diastereoselective formal [3 + 3]-cycloaddition, and a transannular Mannich reaction to construct the core of the natural product." @default.
- W2069532098 created "2016-06-24" @default.
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- W2069532098 date "2010-06-22" @default.
- W2069532098 modified "2023-10-18" @default.
- W2069532098 title "Total Synthesis of (+)-Fastigiatine" @default.
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- W2069532098 doi "https://doi.org/10.1021/ja104575h" @default.
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