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- W2069593340 abstract "Palladium-catalyzed diacetoxylation of 5,6-isopropylendioxy-1,3-cyclohexadiene (3) was stereoselective and gave the trans-diacetate 4 (>94% trans), which after hydrolysis and deprotection, afforded (±)-conduritol. Enzymatic hydrolysis of diacetate 4 produced enantiomerically pure diol (−)-5 (>99.5% ee) and enantiomerically pure (+)-4 (>99.5% ee). Compounds (−)-5 and (+)-4 were subsequently transformed to (−)- and (+)-conduritol C, respectively." @default.
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- W2069593340 date "1998-11-20" @default.
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- W2069593340 title "Efficient Synthesis of (±)-, (+)-, and (−)-Conduritol C via Palladium(II)-Catalyzed 1,4-Diacetoxylation in Combination with Enzymatic Hydrolysis" @default.
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- W2069593340 doi "https://doi.org/10.1021/jo981281k" @default.
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