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- W2069656439 abstract "Differential scanning calorimetry on powders and x-ray diffraction on single crystals of $({mathrm{CH}}_{3}{)}_{4}mathrm{NSCN}$ reveal a cell-doubling cubic-to-orthorhombic ${(O}_{h}^{1}ensuremath{rightarrow}{D}_{2h}^{13})$ ferroelastic transition at 181 ifmmode^circelsetextdegreefi{}C. This transformation is interpreted as a two-step mechanism in which an incomplete ordering of the SCN groups triggers the ferroelastic deformation via an intermediate tetragonal or orthorhombic phase. Diffuse scattering and diffraction patterns under stress illustrate the theoretical argumentation." @default.
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- W2069656439 date "1999-06-01" @default.
- W2069656439 modified "2023-09-26" @default.
- W2069656439 title "Ferroelastic transition triggered by an ordering mechanism in[(CH3)4N]SCN" @default.
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- W2069656439 doi "https://doi.org/10.1103/physrevb.59.14246" @default.
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