Matches in SemOpenAlex for { <https://semopenalex.org/work/W2069662012> ?p ?o ?g. }
- W2069662012 endingPage "380" @default.
- W2069662012 startingPage "369" @default.
- W2069662012 abstract "The aromatic thioketone xanthione has been investigated by means of the optically detected magnetic resonance (ODMR) technique in a n-hexane matrix at ≈ 1.1 K. It was established that the short-lived red emission, which is characteristic for many thione molecules, is phosphorescence. At high temperatures (77 K) this phosphorescence originates mainly (>80%) from the T1z (n, π*) sublevel (kz(r) >kx(r), ky(r). At low temperature (1.1 K) the intersystem crossing following S2 (π, π*) ← S0 excitation is a highly spin-sublevel selective process which populates predominantly the T1x and T1y, levels. Hence, the slow spin—lattice relaxation phosphorescence at low temperature originates from these sublevels. A value of 0.0611 cm−1 was obtained for the zero-field parameter |E|/hc. A lower limit of 0.66 cm−1 has been found for the zero-field parameter |D|/hc. This value is considerably larger than those observed for ketones, and it is shown that spin—orbit coupling contributes strongly to the zero-field splitting." @default.
- W2069662012 created "2016-06-24" @default.
- W2069662012 creator A5049702210 @default.
- W2069662012 creator A5057960044 @default.
- W2069662012 creator A5069759849 @default.
- W2069662012 date "1978-08-01" @default.
- W2069662012 modified "2023-09-27" @default.
- W2069662012 title "Optically detected magnetic resonance study of the lowest excited triplet state of aromatic thioketones: Xanthione" @default.
- W2069662012 cites W1624229382 @default.
- W2069662012 cites W1967140358 @default.
- W2069662012 cites W1971996662 @default.
- W2069662012 cites W1978095751 @default.
- W2069662012 cites W1980994698 @default.
- W2069662012 cites W1994178657 @default.
- W2069662012 cites W2016567550 @default.
- W2069662012 cites W2018295620 @default.
- W2069662012 cites W2022517423 @default.
- W2069662012 cites W2023971622 @default.
- W2069662012 cites W2029554343 @default.
- W2069662012 cites W2033497080 @default.
- W2069662012 cites W2036957812 @default.
- W2069662012 cites W2046396112 @default.
- W2069662012 cites W2052243888 @default.
- W2069662012 cites W2059858200 @default.
- W2069662012 cites W2062245068 @default.
- W2069662012 cites W2062250132 @default.
- W2069662012 cites W2064708952 @default.
- W2069662012 cites W2071604861 @default.
- W2069662012 cites W2075902657 @default.
- W2069662012 cites W2078161640 @default.
- W2069662012 cites W2082255451 @default.
- W2069662012 cites W2083378429 @default.
- W2069662012 cites W2084020833 @default.
- W2069662012 cites W2088148920 @default.
- W2069662012 cites W2802618684 @default.
- W2069662012 cites W2956022115 @default.
- W2069662012 cites W4236911935 @default.
- W2069662012 doi "https://doi.org/10.1016/0301-0104(78)85019-8" @default.
- W2069662012 hasPublicationYear "1978" @default.
- W2069662012 type Work @default.
- W2069662012 sameAs 2069662012 @default.
- W2069662012 citedByCount "35" @default.
- W2069662012 countsByYear W20696620122016 @default.
- W2069662012 countsByYear W20696620122022 @default.
- W2069662012 crossrefType "journal-article" @default.
- W2069662012 hasAuthorship W2069662012A5049702210 @default.
- W2069662012 hasAuthorship W2069662012A5057960044 @default.
- W2069662012 hasAuthorship W2069662012A5069759849 @default.
- W2069662012 hasConcept C121332964 @default.
- W2069662012 hasConcept C131538251 @default.
- W2069662012 hasConcept C139210041 @default.
- W2069662012 hasConcept C147120987 @default.
- W2069662012 hasConcept C178790620 @default.
- W2069662012 hasConcept C181500209 @default.
- W2069662012 hasConcept C181817918 @default.
- W2069662012 hasConcept C184779094 @default.
- W2069662012 hasConcept C185592680 @default.
- W2069662012 hasConcept C21690051 @default.
- W2069662012 hasConcept C32909587 @default.
- W2069662012 hasConcept C33062035 @default.
- W2069662012 hasConcept C40567970 @default.
- W2069662012 hasConcept C41999313 @default.
- W2069662012 hasConcept C62520636 @default.
- W2069662012 hasConcept C73978554 @default.
- W2069662012 hasConcept C76766466 @default.
- W2069662012 hasConcept C83581075 @default.
- W2069662012 hasConcept C91881484 @default.
- W2069662012 hasConceptScore W2069662012C121332964 @default.
- W2069662012 hasConceptScore W2069662012C131538251 @default.
- W2069662012 hasConceptScore W2069662012C139210041 @default.
- W2069662012 hasConceptScore W2069662012C147120987 @default.
- W2069662012 hasConceptScore W2069662012C178790620 @default.
- W2069662012 hasConceptScore W2069662012C181500209 @default.
- W2069662012 hasConceptScore W2069662012C181817918 @default.
- W2069662012 hasConceptScore W2069662012C184779094 @default.
- W2069662012 hasConceptScore W2069662012C185592680 @default.
- W2069662012 hasConceptScore W2069662012C21690051 @default.
- W2069662012 hasConceptScore W2069662012C32909587 @default.
- W2069662012 hasConceptScore W2069662012C33062035 @default.
- W2069662012 hasConceptScore W2069662012C40567970 @default.
- W2069662012 hasConceptScore W2069662012C41999313 @default.
- W2069662012 hasConceptScore W2069662012C62520636 @default.
- W2069662012 hasConceptScore W2069662012C73978554 @default.
- W2069662012 hasConceptScore W2069662012C76766466 @default.
- W2069662012 hasConceptScore W2069662012C83581075 @default.
- W2069662012 hasConceptScore W2069662012C91881484 @default.
- W2069662012 hasIssue "3" @default.
- W2069662012 hasLocation W20696620121 @default.
- W2069662012 hasOpenAccess W2069662012 @default.
- W2069662012 hasPrimaryLocation W20696620121 @default.
- W2069662012 hasRelatedWork W175704366 @default.
- W2069662012 hasRelatedWork W2009457979 @default.
- W2069662012 hasRelatedWork W2020692080 @default.
- W2069662012 hasRelatedWork W2315473776 @default.
- W2069662012 hasRelatedWork W26746109 @default.
- W2069662012 hasRelatedWork W3088182718 @default.
- W2069662012 hasRelatedWork W3112844512 @default.
- W2069662012 hasRelatedWork W3149507045 @default.