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- W2069672178 abstract "The scrambling due to the spin—orbit coupling of the lowest excited singlet states 1 T 1g and 1 T 2g with 3 T 1g of diamagnetic Co(III) complexes is considered. Using a molecular orbital approach, this mixing is shown to account for the observed intensity of the 1 A 1g →3 T 1g band. Specifically it is found that it is the heavy atoms in the molecule which determines the intensity of the transition. This qualitatively explains the increasing intensity of the spin-forbidden band in the series of complexes Co(NH3)6 +3, Co(NH3)5F+2, Co(NH3)5Cl+2, Co(NH3)5Br+2 and Co(NH3)5I+2. Furthermore, the rotatory strength of the spin-forbidden band in Co(en)3 +3 is shown to be about 1 per cent of the rotatory strength for the 1 A 1→1 T 1 band." @default.
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- W2069672178 date "1963-06-01" @default.
- W2069672178 modified "2023-09-27" @default.
- W2069672178 title "The intensity and rotatory strength of the spin-forbidden Co(III) absorption band" @default.
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- W2069672178 doi "https://doi.org/10.1080/00268976300100511" @default.
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