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- W2069682022 abstract "The effects of finite ion size and polyion concentration on the adsorption isotherms are examined within the context of a one-dimensional lattice restricted to nearest-neighbor interactions. The nearest-neighbor interactions include that of the bound ion with adjacent lattice sites as well as with a neighbor bound ion. Both screened and unscreened Coulombic interactions are employed, as they are shown to exhibit different behaviors under high salt concentrations. For the screened interactions, previously adsorbed ions are released, whereas for the unscreened Coulombic interaction charge reversal is observed for sufficiently separated lattice sites. The effect of polyion concentration is to provide a “constant” degree of adsorption for added salt concentrations less than the concentration of counterions released by the polyion. The model is applied to experimental data on monovalent and divalent salts." @default.
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- W2069682022 date "1999-03-12" @default.
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- W2069682022 title "Adsorption Layer of Charged Surfaces: An Exact Nearest-Neighbor Model for the Linear Lattice" @default.
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- W2069682022 doi "https://doi.org/10.1021/la9805746" @default.
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