Matches in SemOpenAlex for { <https://semopenalex.org/work/W2069761119> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W2069761119 endingPage "2594" @default.
- W2069761119 startingPage "2591" @default.
- W2069761119 abstract "The effect of pressure to 200 kbar has been measured on the Mössbauer resonance in potassium ferrocyanide, potassium ferricyanide, and insoluble Prussian blue. The ferrocyanide exhibits a decrease of isomer shift with pressure large compared with typical high-spin ionic ferrous compounds. The ferricyanide exhibits an initial shift with pressure twice as large as the ferrous material. These large changes can be associated with changes in ``back donation'' and in 4s admixture in the binding. The ferricyanide reduces to ferrous compound with increasing pressure, paralleling to behavior of many high-spin ferric compounds. As in the case of the high-spin material, the phenomenon reverses with decreasing pressure. Near 50 kbar a first-order phase transition occurs which apperantly relieves the internal compression of the ferricyanide ion. It is accompanied by an increase in the isomer shift of the ferric ion and the pressure-induced ferrous ion as well as a decrease in the quadrupole splitting of the former. It is also accompanied by a large decrease in the percentage of Fe2+ ion present. This definitely relates the reversible reduction of ferric iron to overlap of the wavefunctions of metal and ligand. Insoluble Prussion blue contains high-spin ferric ion and low-spin ferrous ion. This compound also shows a reversible reduction of high-spin ferric ion with increasing pressure." @default.
- W2069761119 created "2016-06-24" @default.
- W2069761119 creator A5002164027 @default.
- W2069761119 creator A5080498091 @default.
- W2069761119 date "1967-10-15" @default.
- W2069761119 modified "2023-09-27" @default.
- W2069761119 title "Effect of Pressure on the Mössbauer Resonance in Potassium Ferrocyanide, Potassium Ferricyanide, and Insoluble Prussian Blue" @default.
- W2069761119 cites W1981998901 @default.
- W2069761119 cites W2003067437 @default.
- W2069761119 cites W2003152800 @default.
- W2069761119 cites W2026388205 @default.
- W2069761119 cites W2035883814 @default.
- W2069761119 cites W2060241323 @default.
- W2069761119 cites W2066614388 @default.
- W2069761119 cites W2066683280 @default.
- W2069761119 cites W2328298691 @default.
- W2069761119 doi "https://doi.org/10.1063/1.1712274" @default.
- W2069761119 hasPublicationYear "1967" @default.
- W2069761119 type Work @default.
- W2069761119 sameAs 2069761119 @default.
- W2069761119 citedByCount "47" @default.
- W2069761119 countsByYear W20697611192013 @default.
- W2069761119 countsByYear W20697611192015 @default.
- W2069761119 countsByYear W20697611192016 @default.
- W2069761119 countsByYear W20697611192019 @default.
- W2069761119 countsByYear W20697611192021 @default.
- W2069761119 countsByYear W20697611192023 @default.
- W2069761119 crossrefType "journal-article" @default.
- W2069761119 hasAuthorship W2069761119A5002164027 @default.
- W2069761119 hasAuthorship W2069761119A5080498091 @default.
- W2069761119 hasConcept C147789679 @default.
- W2069761119 hasConcept C17525397 @default.
- W2069761119 hasConcept C178790620 @default.
- W2069761119 hasConcept C179104552 @default.
- W2069761119 hasConcept C185592680 @default.
- W2069761119 hasConcept C2775832776 @default.
- W2069761119 hasConcept C2776043530 @default.
- W2069761119 hasConcept C2777411777 @default.
- W2069761119 hasConcept C2777661988 @default.
- W2069761119 hasConcept C2779064266 @default.
- W2069761119 hasConcept C2779451542 @default.
- W2069761119 hasConcept C2780534640 @default.
- W2069761119 hasConcept C2781307518 @default.
- W2069761119 hasConcept C52859227 @default.
- W2069761119 hasConcept C70854507 @default.
- W2069761119 hasConcept C8010536 @default.
- W2069761119 hasConceptScore W2069761119C147789679 @default.
- W2069761119 hasConceptScore W2069761119C17525397 @default.
- W2069761119 hasConceptScore W2069761119C178790620 @default.
- W2069761119 hasConceptScore W2069761119C179104552 @default.
- W2069761119 hasConceptScore W2069761119C185592680 @default.
- W2069761119 hasConceptScore W2069761119C2775832776 @default.
- W2069761119 hasConceptScore W2069761119C2776043530 @default.
- W2069761119 hasConceptScore W2069761119C2777411777 @default.
- W2069761119 hasConceptScore W2069761119C2777661988 @default.
- W2069761119 hasConceptScore W2069761119C2779064266 @default.
- W2069761119 hasConceptScore W2069761119C2779451542 @default.
- W2069761119 hasConceptScore W2069761119C2780534640 @default.
- W2069761119 hasConceptScore W2069761119C2781307518 @default.
- W2069761119 hasConceptScore W2069761119C52859227 @default.
- W2069761119 hasConceptScore W2069761119C70854507 @default.
- W2069761119 hasConceptScore W2069761119C8010536 @default.
- W2069761119 hasIssue "8" @default.
- W2069761119 hasLocation W20697611191 @default.
- W2069761119 hasOpenAccess W2069761119 @default.
- W2069761119 hasPrimaryLocation W20697611191 @default.
- W2069761119 hasRelatedWork W1981302969 @default.
- W2069761119 hasRelatedWork W2001123445 @default.
- W2069761119 hasRelatedWork W2009869620 @default.
- W2069761119 hasRelatedWork W2011715586 @default.
- W2069761119 hasRelatedWork W2051114710 @default.
- W2069761119 hasRelatedWork W2059356909 @default.
- W2069761119 hasRelatedWork W2069761119 @default.
- W2069761119 hasRelatedWork W2094301852 @default.
- W2069761119 hasRelatedWork W2130315192 @default.
- W2069761119 hasRelatedWork W2605648834 @default.
- W2069761119 hasVolume "47" @default.
- W2069761119 isParatext "false" @default.
- W2069761119 isRetracted "false" @default.
- W2069761119 magId "2069761119" @default.
- W2069761119 workType "article" @default.