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- W2069762177 abstract "A microfiltration−HPLC technique which was recently introduced is applied to the study of the uptake of atrazine (2-chloro-4-(ethylamino)-6-(isopropylamino)-s-triazine) by a mineral soil, Green Belt BG 843. The uptake can be partitioned into labile and nonlabile contributions. Each process shows a saturation limit consistent with a “complexation site” model of atrazine binding. The indications of a definite and low stoichiometry of uptake capacity is a key result of this analysis. The labile sorption capacity, θc, is 0.40 × 10-6 mol g-1. At 25 °C an equilibrium constant, K1, for the labile sorption is 3.0 × 104 M-1, and the apparent diffusion coefficient for nonlabile uptake is 8.8 × 10-11 cm2 s-1, corresponding to a first-order rate constant of 9.6 × 10-7 s-1. Preliminary indications are that the capacity of nonlabile binding sites is <10-4 mol g-1. Keywords: Atrazine−soil interactions; on-line HPLC microextraction; bound residues; intraparticle diffusion; sorption capacity; sorption mechanisms" @default.
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- W2069762177 date "1996-01-01" @default.
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- W2069762177 title "Atrazine Sorption by a Mineral Soil: Processes of Labile and Nonlabile Uptake" @default.
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- W2069762177 doi "https://doi.org/10.1021/jf950500p" @default.
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