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- W2069787411 abstract "Abstract Layered double hydroxides with a high layer charge (+0.33 per empirical formula unit) intercalate nitrate ions with the molecular plane of the NO 3 – ion inclined at ca. 70° to the metal hydroxide layer, which results in a basal spacing of 8.8 Å. Three different N–O bond lengths are observed and yield C s coordination symmetry. At lower charge (0.165 ≤ x ≤ 0.2), a basal spacing of 8.0 Å is observed, which indicates that the nitrate ion is intercalated with its molecular plane parallel to the metal hydroxide layer (coordination symmetry D 3 h ) in a manner isostructural with carbonate‐intercalated layered double hydroxides. Consequently, crystal chemical considerations predict the layer charge corresponding to the idealized composition of the nitrate‐intercalated phase to be +0.165 per empirical formula unit. The [Mg–Al–NO 3 ] 0.165 phase is highly ordered with robust crystal growth along [001] and is stable to hydrothermal treatment, in contrast to the carbonate analogue of the same layer charge. Phases obtained with intermediate layer charge (+0.20 to 0.25 per empirical formula unit) exhibit structural disorder arising out of (i) planar faults and (ii) random interstratification of layers comprising nitrate ions in different orientations." @default.
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- W2069787411 date "2013-02-18" @default.
- W2069787411 modified "2023-10-11" @default.
- W2069787411 title "Nitrate‐Intercalated Layered Double Hydroxides – Structure Model, Order, and Disorder" @default.
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- W2069787411 doi "https://doi.org/10.1002/ejic.201201405" @default.
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