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- W2069789562 abstract "A single linear flexible polymer chain has many degrees of internal rotational freedom about its single bonds. Moreover, there exist irregular translational and rotational motions of the entire molecule. It is assumed that the chain is composed of a number of elements joined in succession. From the macroscopic point of view, these elements can be considered as “particles” with a limited degree of freedom to move. Due to the interaction of the chain with itself or with neighbors, thre also exist “defects” in the conformation of the chain. They are mobile due to the action of external “forces” and their interaction with the elements of the chain causes a local reorientation and relaxation of the element-“particle”. According to this picture, one can assume that the diffusion of “defects” may start the relaxation process in a polymeric system. It is possible to apply the defect-diffusion model to mechanical deformations of the system." @default.
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- W2069789562 date "1988-01-01" @default.
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- W2069789562 title "Simulation of rheological properties of polymeric fluids" @default.
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- W2069789562 doi "https://doi.org/10.1016/0895-7177(88)90640-1" @default.
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