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- W2069807029 endingPage "55" @default.
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- W2069807029 abstract "By means of X-ray diffraction (XRD), N2 adsorption-desorption, Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), NH3-temperature (NH3-TPD), Py-infrared (Py-IR) and thermogravimetry-differential scanning calorimetry (TG/DTA) techniques, the influences of Ce on the structure, acidity, stability and hydroisomerization performance of Ni-HPW/MCM-48 and Ni-HPW/Ce-MCM-48 catalysts were studied. The results showed that introduction of appropriate content of Ce into MCM-48 could improve the crystallinity, acidity and stability of mesoporous silica. The acidity and stability of the Ni-HPW/Ce-MCM-48 catalyst was also increased. Besides, the catalytic performance of the Ni-HPW/Ce-MCM-48 catalyst for n-heptane hydroisomerization was promoted. The conversion and selectivity of the Ni-HPW/Ce-MCM-48 catalyst reached 41% and 91% respectively at the preparation conditions of 4 wt.% Ni, 20 wt.% HPW, 0.03 Ce/Si molar ratio." @default.
- W2069807029 created "2016-06-24" @default.
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- W2069807029 date "2015-01-01" @default.
- W2069807029 modified "2023-10-06" @default.
- W2069807029 title "Influences of cerium on structure and catalytic performance of n-heptane hydroisomerization of Ni-HPW/MCM-48" @default.
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- W2069807029 doi "https://doi.org/10.1016/s1002-0721(14)60382-3" @default.
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