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• W2069818098 abstract "Both diastereoisomeric forms of [Ru2(dppcb)(bipy)4]4+, where dppcb is cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphino)cyclobutane, show a completely unexpected photochemical reactivity. In acetonitrile, a ligand exchange reaction produces [Ru2(dppcb)(bipy)2(MeCN)4]4+. To the best of our knowledge, dppcb is the first phosphine leading to this reaction type. A careful examination of the X-ray structures of the diastereoisomerically pure forms of [Ru2(dppcb)(bipy)4]4+ and of [Ru2(dppcb)(bipy)2(MeCN)4]4+ reveals that the release of steric strain observable as the disappearance of mechanical coupling is responsible for this reactivity." @default.
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• W2069818098 date "2001-11-30" @default.
• W2069818098 modified "2023-09-24" @default.
• W2069818098 title "Unexpected Photochemical Reactivity of Ruthenium(II) Polypyridine Complexes Induced by a Bis(bidentate) Phosphine" @default.
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• W2069818098 doi "https://doi.org/10.1021/ic010545+" @default.
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