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- W2069842911 abstract "Ring slippage of the indenyl occurs upon dissolution of the complexes [η5-IndM(CO)2L2]BF4 (M=Mo of W; L=NCMe or dimethylformamide) in an excess of L, to give [(η3-Ind)M(CO)2L3]Bf4. Other ring-slipped complexes synthesized are [(η3-Ind)Mo(CO)2L3]BF4 (L3=HC(pz)3, [HB(pz)3]−, Me3tacn or {en(NCMe)}). Addition of NCMe or an excess of L failed to give ring slippage in [η5-IndMo(CO)2L2]BF4 (L2=bipy, dppe, (PMe3)2, {P(OMe)3}2 or triphos). NMR and X-ray studies reveal a large folding of the η3-indenyl ring. The structure complex [(η3-Ind)W(CO)2(NCMe)3]BF4 (5) was determined by X-ray analysis." @default.
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- W2069842911 date "1996-02-01" @default.
- W2069842911 modified "2023-10-16" @default.
- W2069842911 title "Ring slippage in indenyl derivatives of molybdenum and tungsten" @default.
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- W2069842911 doi "https://doi.org/10.1016/0022-328x(95)05859-n" @default.
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