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- W2069867618 abstract "Abstract The infra-red spectrum of [Co(en) 3 ]Cl 3 ·3T 2 O has been observed over a period of 5 months. The spectrum changes considerably even in 2 days after preparation of the hydrate, revealing quite different features from the parent. Initially some bands due to the NH 2 group disappear, while new bands appear. These are explained in terms of a change in bonding character or as an interaction between the complex ion and the chloride anion in the crystal. Subsequently, the bands due to ethylenediamine decrease in intensity and almost vanish, while additional new bands appear. The new bands are explained in terms of ammine complexes. It is proposed that a decomposition reaction of en → 2NH 3 + HCCH takes place through intermediates such as vinylamine and so on. After one month the spectrum still changes slowly with further new bands due to a HT exchange reaction." @default.
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- W2069867618 date "1987-01-01" @default.
- W2069867618 modified "2023-09-26" @default.
- W2069867618 title "The infra-red spectrum of [Co(en)3]Cl3·3T2O (en: ethylenediamine)" @default.
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- W2069867618 doi "https://doi.org/10.1016/0584-8539(87)80224-6" @default.
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