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- W2069875587 abstract "Abstract A new synthetic method of obtaining 4-fluorophenol starting from fluorobenzene is reported. The process involves three steps: 1. formation of 4-F,4′-Z-benzophenones by a Friedel-Crafts condensation between fluorobenzene and 4-Z-benzoyl chlorides; 2. oxidation of the benzophenone-derivatives to the corresponding arylesters by peracetic acid; 3. alkaline hydrolysis of the esters giving the final 4-fluorophenol. The influence on the reaction selectivity deriving from the electrophilic character of the different Z-substituents in the benzoyl chlorides moiety has been also investigated." @default.
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- W2069875587 date "1992-08-01" @default.
- W2069875587 modified "2023-09-26" @default.
- W2069875587 title "New synthetic route to 4-fluorophenol by the Baeyer-Villiger reaction" @default.
- W2069875587 doi "https://doi.org/10.1016/s0022-1139(00)80595-3" @default.
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