Matches in SemOpenAlex for { <https://semopenalex.org/work/W2069883362> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W2069883362 endingPage "555" @default.
- W2069883362 startingPage "545" @default.
- W2069883362 abstract "Evidence for the existence of the outer-sphere ion-pair Cr(H2O)63+.Cl− in aqueous solutions containing chromium(III) and chloride is presented. The stability constant for the formation of the species has been determined at different fixed temperatures for solutions of ionic strength 1 M maintained with perchloric acid. The formation constant at 40° of the inner-sphere complex Cr(H2O)5Cl2+ has also been derived. A solvent extraction method and 51Cr as tracer were used for the measurements. Démonstration de l'existence de paires d'ions à symétrie sphérique Cr(H2O)63+.Cl− dans des solutions aqueuses de chrome III et de chlorure. La constante de stabilité de ces espèces a été déterminée à différentes températures dans des solutions de force ionique 1 M imposée au moyen d'acide perchlorique. La constante de formation à 40° du complexe sphérique interne Cr(H2O)5Cl2+ a aussi été obtenue. Une méthode par extraction de solvant, avec 51 Cr comme traceur, a été utilisée pour les mesures. Es wird experimentelles Material vorgelegt, welches die postulierte Existenz des Ionenpaares äusserer Sphäre Cr(H2O)63+.Cl− in wässrigen, Chrom (III) und Chlorid enthaltenden Lösungen bestätigt. Man ermittelte die Stabilitätskonstanten der Bildung dieses Komplexes bei verschiedenen Temperaturen in Perchlorsäure-Lösungen der Ionenstärke 1 M. Die Bildungskonstante des Komplexes innerer Sphäre Cr(H2O)5Cl2+ wurde bei 40°C ebenfalls ermittelt. Für die Messungen benützte man 51Cr als “Tracer” zusammen mit einer Lösungsmittel-Extraktionsmethode." @default.
- W2069883362 created "2016-06-24" @default.
- W2069883362 creator A5003962536 @default.
- W2069883362 creator A5021576199 @default.
- W2069883362 date "1968-03-01" @default.
- W2069883362 modified "2023-09-27" @default.
- W2069883362 title "A study of chromium(III) chloride complexes using chromium-51 as tracer" @default.
- W2069883362 cites W1977447361 @default.
- W2069883362 cites W1988998680 @default.
- W2069883362 cites W1992210899 @default.
- W2069883362 cites W2003553602 @default.
- W2069883362 cites W2013816035 @default.
- W2069883362 cites W2015443569 @default.
- W2069883362 cites W2017756671 @default.
- W2069883362 cites W2021895901 @default.
- W2069883362 cites W2023351185 @default.
- W2069883362 cites W2024841790 @default.
- W2069883362 cites W2025714146 @default.
- W2069883362 cites W2046359470 @default.
- W2069883362 cites W2048255241 @default.
- W2069883362 cites W2052840000 @default.
- W2069883362 cites W2062683633 @default.
- W2069883362 cites W2064442397 @default.
- W2069883362 cites W2080663634 @default.
- W2069883362 cites W2083867495 @default.
- W2069883362 cites W2089036670 @default.
- W2069883362 cites W2089636558 @default.
- W2069883362 cites W2095393128 @default.
- W2069883362 cites W2096677335 @default.
- W2069883362 cites W2315275429 @default.
- W2069883362 cites W2316337531 @default.
- W2069883362 cites W2317949816 @default.
- W2069883362 cites W2320145226 @default.
- W2069883362 cites W2325418423 @default.
- W2069883362 cites W2325694971 @default.
- W2069883362 cites W2331734563 @default.
- W2069883362 cites W2332572079 @default.
- W2069883362 doi "https://doi.org/10.1016/0013-4686(68)87025-2" @default.
- W2069883362 hasPublicationYear "1968" @default.
- W2069883362 type Work @default.
- W2069883362 sameAs 2069883362 @default.
- W2069883362 citedByCount "17" @default.
- W2069883362 countsByYear W20698833622016 @default.
- W2069883362 countsByYear W20698833622019 @default.
- W2069883362 crossrefType "journal-article" @default.
- W2069883362 hasAuthorship W2069883362A5003962536 @default.
- W2069883362 hasAuthorship W2069883362A5021576199 @default.
- W2069883362 hasConcept C13965031 @default.
- W2069883362 hasConcept C147789679 @default.
- W2069883362 hasConcept C178790620 @default.
- W2069883362 hasConcept C179104552 @default.
- W2069883362 hasConcept C184651966 @default.
- W2069883362 hasConcept C185592680 @default.
- W2069883362 hasConcept C2778161354 @default.
- W2069883362 hasConcept C2778695967 @default.
- W2069883362 hasConcept C2992805683 @default.
- W2069883362 hasConcept C43617362 @default.
- W2069883362 hasConcept C4725764 @default.
- W2069883362 hasConcept C511782168 @default.
- W2069883362 hasConceptScore W2069883362C13965031 @default.
- W2069883362 hasConceptScore W2069883362C147789679 @default.
- W2069883362 hasConceptScore W2069883362C178790620 @default.
- W2069883362 hasConceptScore W2069883362C179104552 @default.
- W2069883362 hasConceptScore W2069883362C184651966 @default.
- W2069883362 hasConceptScore W2069883362C185592680 @default.
- W2069883362 hasConceptScore W2069883362C2778161354 @default.
- W2069883362 hasConceptScore W2069883362C2778695967 @default.
- W2069883362 hasConceptScore W2069883362C2992805683 @default.
- W2069883362 hasConceptScore W2069883362C43617362 @default.
- W2069883362 hasConceptScore W2069883362C4725764 @default.
- W2069883362 hasConceptScore W2069883362C511782168 @default.
- W2069883362 hasIssue "3" @default.
- W2069883362 hasLocation W20698833621 @default.
- W2069883362 hasOpenAccess W2069883362 @default.
- W2069883362 hasPrimaryLocation W20698833621 @default.
- W2069883362 hasRelatedWork W1436451276 @default.
- W2069883362 hasRelatedWork W1976095424 @default.
- W2069883362 hasRelatedWork W1983621537 @default.
- W2069883362 hasRelatedWork W2009563529 @default.
- W2069883362 hasRelatedWork W2027342980 @default.
- W2069883362 hasRelatedWork W2029825652 @default.
- W2069883362 hasRelatedWork W2075335675 @default.
- W2069883362 hasRelatedWork W2266120070 @default.
- W2069883362 hasRelatedWork W2419569430 @default.
- W2069883362 hasRelatedWork W3111042817 @default.
- W2069883362 hasVolume "13" @default.
- W2069883362 isParatext "false" @default.
- W2069883362 isRetracted "false" @default.
- W2069883362 magId "2069883362" @default.
- W2069883362 workType "article" @default.