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• W2069893257 abstract "Grain growth mechanisms of calcium carbonate doped with lithium phosphate were determined. With small lithium phosphate addition, an abnormal needle-like grain growth was observed. Addition of the dopant as solid solution in calcite follows the equation: Li3PO4CaCO3→3(Lii+)+ + VCa2+2− + (PO43−)CO32+−. In slightly higher quantities (2 wt.%) above the solubility limit of Li3PO4, a second phase segregated at the grain boundaries. Whatever the thermal treatment (temperature, CO2 partial pressure), the grain distribution was self-similar (G(t)/G(t))=time independent) and followed a single log normal law. The grain growth kinetics can be described by the equation: dG/dt=k(G−1-Gc−1). The grain growth was controlled by the mobility of the second phase." @default.
• W2069893257 created "2016-06-24" @default.
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• W2069893257 date "1997-11-01" @default.
• W2069893257 modified "2023-10-18" @default.
• W2069893257 title "Grain growth kinetics of Li3PO4-doped calcium carbonate" @default.
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• W2069893257 doi "https://doi.org/10.1016/s0167-2738(97)84077-5" @default.
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