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• W2069912725 abstract "Optical absorption spectra have been measured at pressures up to 80 gigapascals (GPa) for the lower-mantle oxide magnesiowüstite (Mg,Fe)O. Upon reaching the high-spin to low-spin transition of Fe 2+ at about 60 GPa, we observed enhanced absorption in the mid- and near-infrared spectral range, whereas absorption in the visible-ultraviolet was reduced. The observed changes in absorption are in contrast to prediction and are attributed to d-d orbital charge transfer in the Fe 2+ ion. The results indicate that low-spin (Mg,Fe)O will exhibit lower radiative thermal conductivity than high-spin (Mg,Fe)O, which needs to be considered in future geodynamic models of convection and plume stabilization in the lower mantle." @default.
• W2069912725 created "2016-06-24" @default.
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• W2069912725 date "2006-05-26" @default.
• W2069912725 modified "2023-10-16" @default.
• W2069912725 title "Reduced Radiative Conductivity of Low-Spin (Mg,Fe)O in the Lower Mantle" @default.
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• W2069912725 doi "https://doi.org/10.1126/science.1125622" @default.
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