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• W2069913816 abstract "The chair and twist-chair conformations of seven-membered rings are classified as a function of the signs of their endocyclic torsion angles. The conformational analysis (MM3) of the methoxy- and methyloxepanes 1-6 used as patterns allows the study and classification of the different types of hydrogen orientation in the seven-membered saturated heterocycles. General principles are established, allowing the prediction of the stability of the different twist-chair conformations as a function of the substituent type, its position in the ring, and the type of hydrogen atom that has been substituted. These results are extended to the 1,4-dioxepane derivatives 7-13 and are compared with experimental data." @default.
• W2069913816 created "2016-06-24" @default.
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• W2069913816 date "1997-01-01" @default.
• W2069913816 modified "2023-10-02" @default.
• W2069913816 title "A New Systematization of the Conformational Behavior of Seven-Membered Rings. Isoclinal Anomeric and Related Orientations¹" @default.
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• W2069913816 doi "https://doi.org/10.1021/jo951950j" @default.
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