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- W2069930123 abstract "The voltammetric properties of the Keggin-type [XW12O40]n− complexes were compared with those of the corresponding Mo-analogues, [XMo12O40]n−, where X=P, Ge; n=3, 4. The one-electron waves for the Keggin anions are converted into two-electron waves by the presence of small cations such as H+, Li+ and Na+, and the conversion occurs much more easily for [XMo12O40]n−, as compared with [XW12O40]n− with an identical ionic charge. A comparison of the redox potentials for the V(V)/V(IV) couple of the mono-vanadium derivatives made it possible to estimate the ionic radius of [XMo12O40]n− as 5.4 Å, with the ionic radius of [XW12O40]n−=5.6 Å as reference. The big difference in voltammetric behaviors between the Mo- and W-complexes was interpreted in terms of the smaller ionic radius and consequently greater basicity of [XMo12O40]3/4−, as compared with [XW12O40]3/4−." @default.
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- W2069930123 date "2002-06-01" @default.
- W2069930123 modified "2023-09-24" @default.
- W2069930123 title "Difference in voltammetric properties between the Keggin-type [XW12O40]n− and [XMo12O40]n− complexes" @default.
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- W2069930123 doi "https://doi.org/10.1016/s0022-0728(02)00901-4" @default.
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