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• W2069968294 abstract "A comparative vibrational spectroscopy study is reported for a series of polymer electrolytes composed of poly(oligoethyleneoxy phosphazenes) containing dissolved lithium triflate. These polymers, of the form [NP((OCH2CH2)xOCH3)2]n, with x=0, 1, 2, or 5, have been mixed with LiCF3SO3 in oxygen:lithium concentration ratios ranging from 10:1 to 40:1. Raman vibrational spectroscopy has been used to examine ionic association and local changes of the polymer as the salt concentration and the length of the ethylene oxide side-chains vary. The degree of ionic association of the triflate ion increases with increasing salt concentration. At a given salt concentration, the degree of ionic association and the nature of the ion-polymer interaction are dependent on the length of the side-chains." @default.
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• W2069968294 date "2001-03-01" @default.
• W2069968294 modified "2023-09-26" @default.
• W2069968294 title "A vibrational spectroscopic study of lithium triflate in polyphosphazenes with linear oligoethyleneoxy side-chains of different lengths" @default.
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• W2069968294 doi "https://doi.org/10.1016/s0013-4686(00)00752-0" @default.
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