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- W2069987588 abstract "Maleic hydrazide (3,6-dihydroxypyridazine. I) is reduced to the dicarbonyl form I at the dropping mercury electrode in two-electron waves. The first wave I1 corresponds to a reduction of a diprotonated, the second I2 of a monoprotonated, the third I3 of an unprotonated and the fourth I4 of an anionic form. Exclusion of the dihydroxy form I″ and the monohydroxy form I′ as electroactive species was based on electrochemical properties and comparison of pKa values. Polarographic currents are limited by the rate of protonation occurring as a surface, heterogeneous process. Wave I1 at pH 3 to 5 is the most suitable for analytical applications." @default.
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- W2069987588 date "1997-01-01" @default.
- W2069987588 modified "2023-09-23" @default.
- W2069987588 title "Electroreduction of the hydrazide of maleic acid in aqueous solutions" @default.
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- W2069987588 doi "https://doi.org/10.1016/s0022-0728(96)04817-6" @default.
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