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- W2070024761 abstract "Poly(4-vinylpyridine/styrene) and poly(N-vinyl-2-methylimidazole/styrene) type membranes (SA-14 and SA-15) were prepared as weak-base anion-exchange membranes, and strong-base anion-exchange membranes (SA-14(4) and SA-15(4)) were prepared by quaternizing them with CH3I. Solvent transport across the membranes was measured in electrolyte solutions under a temperature difference. Thermoosmosis toward the cold solution side was clearly observed for membranes SA-14 and SA-15 in KCl and HCl solutions. However, the direction of thermoosmosis was toward the hot side in H2SO4 solutions because the membrane is considerably ionized with H2SO4 and the water in the membrane is more stabilized than that in the external solutions. Thermoosmosis across the quaternized membranes SA-14(4) and SA-15(4) occurred toward the hot side in KCl and KIO3 solutions. The difference between the mean transported entropy of water in the membrane, ⁼s0, and the partial molar entropy of the external solution, s0, was estimated from the thermoosmotic data by combining the experimental data of water flux under an osmotic pressure difference. The values of (⁼s0 − s0) in KCl solutions were positive for membranes SA-14 and SA-15 and negative for membranes SA-14(4) and SA-15(4)." @default.
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- W2070024761 title "Thermoosmosis and Transported Entropy of Water across Poly(4-vinylpyridine/styrene) and Poly(<i>N</i>-vinyl-2-methylimidazole/styrene) Type Membranes in Electrolyte Solutions" @default.
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- W2070024761 doi "https://doi.org/10.1021/jp961850x" @default.
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