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• W2070036207 abstract "O 1s x-ray absorption spectroscopy and first principle calculation have been used to probe the size effect on the orbital character and hybridization of the conduction band of anatase TiO2 nanocrystals over two orders of magnitude in diameter (2-200 nm). The appearance and predominance of unoccupied delocalized states derived from the hybridization of antibonding O 2p and Ti 4s rather than 3d is observed when the nanoparticle size approaches the exciton radius. These results provide an experimental evidence of quantum size effect on unoccupied states in anatase TiO2 nanocrystals." @default.
• W2070036207 created "2016-06-24" @default.
• W2070036207 creator A5029139156 @default.
• W2070036207 creator A5073118003 @default.
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• W2070036207 date "2011-10-31" @default.
• W2070036207 modified "2023-09-28" @default.
• W2070036207 title "Size effect on the conduction band orbital character of anatase TiO2 nanocrystals" @default.
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• W2070036207 doi "https://doi.org/10.1063/1.3657147" @default.
• W2070036207 hasPublicationYear "2011" @default.
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