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- W2070036320 abstract "A convenient synthetic route to prepare amine-terminated poly(ethylene oxide) (PEO) and poly(epsilon-caprolactone) (PCL) was described. The strategy involved two-step reactions, the condensation of hydroxyl-terminated PEO and PCL with N-benzyloxycarbonyl amino acid followed by the catalytic hydrogenation under mild conditions. NMR and GPC measurements indicated that the reactions proceeded nearly quantitatively. Amine-terminated PEO thus prepared was used to initiate the polymerization of alpha-(N(epsilon)-benzyloxycarbonyl-L-lysine) N-carboxy anhydride [lys(Z)-NCA], and the results confirmed that the reactivity of the amino group was high." @default.
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- W2070036320 date "2002-08-14" @default.
- W2070036320 modified "2023-10-16" @default.
- W2070036320 title "A Convenient Method for the Synthesis of Amine-Terminated Poly(ethylene oxide) and Poly(ε-caprolactone)" @default.
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- W2070036320 doi "https://doi.org/10.1021/bc025531m" @default.
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