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- W2070036962 abstract "Abstract Potentially trans ‐chelating diphosphine ligands based on a ferrocenyl‐aryl backbone were synthesised in a four‐step sequence and the molecular structures in the solid state of two representatives were determined by X‐ray diffraction. High throughput screening of these ligands in rhodium‐, ruthenium‐ and iridium‐mediated hydrogenations of a variety of alkenes and ketones revealed that these ligands can deliver high enantioselectivity for alkenes (up to 98% ee ) but are less selective when ketones are used as the substrates. The coordination behaviour of one ligand in its square planar palladium and platinum dichloride complexes was studied by 31 P NMR and only trans ‐chelated complexes, together with oligomeric by‐products, were observed. Reaction with the ( p ‐cymene)ruthenium dichloride dimer, [RuCl 2 ( p ‐cymene)] 2 , resulted in a mixture of diastereomeric complexes." @default.
- W2070036962 created "2016-06-24" @default.
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- W2070036962 date "2010-04-15" @default.
- W2070036962 modified "2023-10-18" @default.
- W2070036962 title "Ferrocenyl-Aryl Based trans-Chelating Diphosphine Ligands: Synthesis, Molecular Structure and Application in Enantioselective Hydrogenation" @default.
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- W2070036962 doi "https://doi.org/10.1002/adsc.200900906" @default.
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