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• W2070049863 abstract "Stereoselective intramolecular 1,3-dipolar cycloaddition of homochiral N-(alkenylglycosyl)nitrones, prepared by allylation of C-(glycosyl)nitrones and subsequent oxidation, is described. The previously described 2-aza-Cope rearrangement was not observed for these substrates, but evidences of E/Z isomerism during the cycloaddition were obtained. The obtained cycloadducts can serve as key precursors of imino disaccharide analogues. This is exemplified by a short route to a protected 2-furanosyl-4-hydroxy-6-phenyl piperidine." @default.
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• W2070049863 date "2009-12-01" @default.
• W2070049863 modified "2023-10-15" @default.
• W2070049863 title "Intramolecular 1,3-dipolar cycloaddition of N-alkenyl nitrones en route to glycosyl piperidines" @default.
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• W2070049863 doi "https://doi.org/10.1016/j.tetlet.2009.10.023" @default.
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