Matches in SemOpenAlex for { <https://semopenalex.org/work/W2070086995> ?p ?o ?g. }
- W2070086995 endingPage "255" @default.
- W2070086995 startingPage "249" @default.
- W2070086995 abstract "The unique properties of reverse micelles, microemulsions, enable a variety of applications, from oil recovery to pharmaceuticals. For an effective process development for a targeted application, systems with specific ionic and molecular transport properties are needed. In this work, experiments were carried out to study microstructures of mixed reverse micelles, microemulsions (water/n-heptane), obtained with the use of anionic surfactants, sodium bis(2-ethylhexyl) sulfosuccinate (AOT) and the structural-related sodium bis(amyl) sulfosuccinate (DAS). Viscosity measurements, electrical conductivity, differential scanning calorimetry (DSC) and small-angle X-ray scattering (SAXS) were experimental techniques used for characterization of the prepared systems. The effect of DAS content on conductivity was that with increasing molar ratio of DAS/AOT (concentration of Na+ cations was kept at constant) the conductivity maximum shifted to lower water content, indicating an enlargement in reverse micelles size, which was also confirmed by SAXS analysis. It was further observed that at total surfactant concentrations of 0.45 mol/L, at a DAS/AOT molar ratio of 10/90, and 0.35 mol/L, at a DAS/AOT molar ratio of 15/85, this maximum almost vanished but an additional conductivity maximum at the composition with higher water content was detected. The effect of DAS on percolation phenomena was striking. The percolation threshold shifted towards smaller water content intensively with an increasing molar ratio of DAS/AOT and DAS concentration to an extent that the conductivity maximum overlapped with the percolation peak. The observed effect and a complementary viscosity and DSC analysis suggested clustering of mixed droplets in the low-water region. It has been confirmed that DAS enables formation of different aggregation states by influencing the rigidity of the oil/water interface in water/AOT-DAS/n-heptane mixed reverse micelles, w/o microemulsions. Our results have shown that by controlling DAS and water content it is possible to extensively modify the microstructure properties of the water/AOT-DAS/n-heptane system." @default.
- W2070086995 created "2016-06-24" @default.
- W2070086995 creator A5001195610 @default.
- W2070086995 creator A5015605301 @default.
- W2070086995 creator A5020652239 @default.
- W2070086995 creator A5050989717 @default.
- W2070086995 creator A5072367411 @default.
- W2070086995 date "2011-07-01" @default.
- W2070086995 modified "2023-10-16" @default.
- W2070086995 title "Characterization of water/sodium bis(2-ethylhexyl) sulfosuccinate/sodium bis(amyl) sulfosuccinate/n-heptane mixed reverse micelles and w/o microemulsion systems: The influence of water and sodium bis(amyl) sulfosuccinate content" @default.
- W2070086995 cites W1979435406 @default.
- W2070086995 cites W1981166227 @default.
- W2070086995 cites W1989534395 @default.
- W2070086995 cites W1992275252 @default.
- W2070086995 cites W1994059747 @default.
- W2070086995 cites W1995981138 @default.
- W2070086995 cites W2021403117 @default.
- W2070086995 cites W2022367796 @default.
- W2070086995 cites W2041622541 @default.
- W2070086995 cites W2054400535 @default.
- W2070086995 cites W2074594474 @default.
- W2070086995 cites W2087947475 @default.
- W2070086995 cites W2090537730 @default.
- W2070086995 cites W2093510937 @default.
- W2070086995 cites W2140947084 @default.
- W2070086995 doi "https://doi.org/10.1016/j.colsurfa.2011.06.018" @default.
- W2070086995 hasPublicationYear "2011" @default.
- W2070086995 type Work @default.
- W2070086995 sameAs 2070086995 @default.
- W2070086995 citedByCount "11" @default.
- W2070086995 countsByYear W20700869952012 @default.
- W2070086995 countsByYear W20700869952013 @default.
- W2070086995 countsByYear W20700869952014 @default.
- W2070086995 countsByYear W20700869952015 @default.
- W2070086995 countsByYear W20700869952016 @default.
- W2070086995 countsByYear W20700869952020 @default.
- W2070086995 countsByYear W20700869952021 @default.
- W2070086995 crossrefType "journal-article" @default.
- W2070086995 hasAuthorship W2070086995A5001195610 @default.
- W2070086995 hasAuthorship W2070086995A5015605301 @default.
- W2070086995 hasAuthorship W2070086995A5020652239 @default.
- W2070086995 hasAuthorship W2070086995A5050989717 @default.
- W2070086995 hasAuthorship W2070086995A5072367411 @default.
- W2070086995 hasConcept C11268172 @default.
- W2070086995 hasConcept C113196181 @default.
- W2070086995 hasConcept C120665830 @default.
- W2070086995 hasConcept C121332964 @default.
- W2070086995 hasConcept C127172972 @default.
- W2070086995 hasConcept C127413603 @default.
- W2070086995 hasConcept C131540310 @default.
- W2070086995 hasConcept C131888329 @default.
- W2070086995 hasConcept C147789679 @default.
- W2070086995 hasConcept C159985019 @default.
- W2070086995 hasConcept C169760540 @default.
- W2070086995 hasConcept C178790620 @default.
- W2070086995 hasConcept C184651966 @default.
- W2070086995 hasConcept C185592680 @default.
- W2070086995 hasConcept C190119865 @default.
- W2070086995 hasConcept C191486275 @default.
- W2070086995 hasConcept C192562407 @default.
- W2070086995 hasConcept C2777854178 @default.
- W2070086995 hasConcept C2780457167 @default.
- W2070086995 hasConcept C39519442 @default.
- W2070086995 hasConcept C42360764 @default.
- W2070086995 hasConcept C43617362 @default.
- W2070086995 hasConcept C537181965 @default.
- W2070086995 hasConcept C55493867 @default.
- W2070086995 hasConcept C58226133 @default.
- W2070086995 hasConcept C86803240 @default.
- W2070086995 hasConcept C97355855 @default.
- W2070086995 hasConceptScore W2070086995C11268172 @default.
- W2070086995 hasConceptScore W2070086995C113196181 @default.
- W2070086995 hasConceptScore W2070086995C120665830 @default.
- W2070086995 hasConceptScore W2070086995C121332964 @default.
- W2070086995 hasConceptScore W2070086995C127172972 @default.
- W2070086995 hasConceptScore W2070086995C127413603 @default.
- W2070086995 hasConceptScore W2070086995C131540310 @default.
- W2070086995 hasConceptScore W2070086995C131888329 @default.
- W2070086995 hasConceptScore W2070086995C147789679 @default.
- W2070086995 hasConceptScore W2070086995C159985019 @default.
- W2070086995 hasConceptScore W2070086995C169760540 @default.
- W2070086995 hasConceptScore W2070086995C178790620 @default.
- W2070086995 hasConceptScore W2070086995C184651966 @default.
- W2070086995 hasConceptScore W2070086995C185592680 @default.
- W2070086995 hasConceptScore W2070086995C190119865 @default.
- W2070086995 hasConceptScore W2070086995C191486275 @default.
- W2070086995 hasConceptScore W2070086995C192562407 @default.
- W2070086995 hasConceptScore W2070086995C2777854178 @default.
- W2070086995 hasConceptScore W2070086995C2780457167 @default.
- W2070086995 hasConceptScore W2070086995C39519442 @default.
- W2070086995 hasConceptScore W2070086995C42360764 @default.
- W2070086995 hasConceptScore W2070086995C43617362 @default.
- W2070086995 hasConceptScore W2070086995C537181965 @default.
- W2070086995 hasConceptScore W2070086995C55493867 @default.
- W2070086995 hasConceptScore W2070086995C58226133 @default.
- W2070086995 hasConceptScore W2070086995C86803240 @default.
- W2070086995 hasConceptScore W2070086995C97355855 @default.
- W2070086995 hasFunder F4320322554 @default.