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- W2070145134 abstract "Abstract Two novel blazeispirol derivatives, blazeispirol D and Z, as the actual intermediates of blazeispirol A biosynthesis have been isolated from the cultured mycelia of Agaricus blazei (Agaricaceae). The structures were elucidated to be (20 S ,22 S ,23 R ,24 S )-14β, 22: 22, 25-diepoxy-des- A -ergosta-5,7,9,11-tetraene-5,23-diol and (20 S ,22 S ,23 R ,24 S )-14β,22:22,25-diepoxy-23-hydroxy-4,5-seco-ergosta-6,8,11-triene-3,5-dione by comparison of extensive 1D and 2D NMR spectral data with that of blazeispirol A. It is discussed that the compounds are the actual intermediates of blazeispirol A biosynthesis." @default.
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- W2070145134 date "2001-07-01" @default.
- W2070145134 modified "2023-09-27" @default.
- W2070145134 title "Blazeispirol D and Z, as the actual intermediates of blazeispirol A biosynthesis from the cultured mycelia of the fungus Agaricus blazei" @default.
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- W2070145134 doi "https://doi.org/10.1016/s0040-4039(01)00949-2" @default.
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