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- W2070145497 abstract "A symmetric diimine ligand containing a CH2PhCH2 bridging group (H2XyTs: N,N′-bis(2-tosylaminobenzylidene)-1,4-xylylenediamine) and its neutral CoII and ZnII dinuclear complexes have been prepared. Two different crystal structures of the free ligand, H2XyTs, and that corresponding to [Co2(XyTs)2], have been solved by X-ray diffraction methods. These revealed two different conformations (syn–anti and anti–anti) for H2XyTs and an infrequent rotational isomerism on the xylylene rings of its CoII dinuclear complex, where both ligands are syn–anti conformed. Characterisation of the compounds is completed with FT-IR, ESI-MS and 1H NMR spectroscopic techniques, when possible." @default.
- W2070145497 created "2016-06-24" @default.
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- W2070145497 date "2006-07-01" @default.
- W2070145497 modified "2023-10-18" @default.
- W2070145497 title "Syn–anti and anti–anti conformations of a diimine derived from p-xylylenediamine and its neutral CoII and ZnII dinuclear complexes" @default.
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- W2070145497 doi "https://doi.org/10.1016/j.ica.2006.02.028" @default.
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