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- W2070152008 endingPage "1064" @default.
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- W2070152008 abstract "We present herein a high yield, highly selective catalytic synthesis of vinylboronate esters (VBEs), including 1,1-disubstituted VBEs, from alkenes without significant hydrogenation or hydroboration, using the simple catalyst precursor, trans-[RhCl(CO)(PPh3)2] (1), and the diboron reagents B2pin2 (2a, pin = pinacolato = OCMe2CMe2O) or B2neop2 (2b, neop = neopentylglycolato = OCH2CMe2CH2O), or the monoboron reagent HBpin, all of which are commercially available. The reactions were conducted at 80 °C using conventional heating, or in a microwave reactor at 150 °C." @default.
- W2070152008 created "2016-06-24" @default.
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- W2070152008 date "2008-01-01" @default.
- W2070152008 modified "2023-10-03" @default.
- W2070152008 title "Rhodium catalysed dehydrogenative borylation of alkenes: Vinylboronates via C–H activation" @default.
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- W2070152008 doi "https://doi.org/10.1039/b715584k" @default.
- W2070152008 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18274686" @default.
- W2070152008 hasPublicationYear "2008" @default.
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