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• W2070166672 abstract "The hydro­thermal reaction of CoCl2·6H2O, 1,10-phenanthroline (phen) and K3[Fe(CN)6] in deionized water yielded the title cyanide-bridged trinuclear cluster, [Co2Fe(CN)8(C12H8N2)4]·4H2O or [{CoIII(phen)(CN)4}2{FeII(phen)2}]·4H2O, which contains two CoIII centers and one FeII center linked by cyanide bridges. The combination of coordinative bonds, O—H⋯N and O—H⋯O hydrogen bonds and π–π stacking inter­actions [centroid–centroid distance = 3.630 (2) Å] results in the stabilization of a supra­molecular structure. All uncoordinated water molecules are disordered. Thermogravimetric analysis reveals that the title complex loses the four crystal water mol­ecules at about 333 K, then the anhydrous phase loses no further mass up to about 573 K, above which decomposition occurs." @default.
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• W2070166672 date "2009-08-08" @default.
• W2070166672 modified "2023-09-24" @default.
• W2070166672 title "Di-μ-cyanido-1:2κ²<i>C</i>:<i>N</i>,2:3κ²<i>N</i>:<i>C</i>-hexacyanido-1κ³<i>C</i>,3κ³<i>C</i>-tetrakis(1,10-phenanthroline)-1κ²<i>N</i>,<i>N</i>′;2κ⁴<i>N</i>,<i>N</i>′;3κ²<i>N</i>,<i>N</i>′-1,3-dicobalt(III)-2-iron(II) tetrahydrate" @default.
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• W2070166672 doi "https://doi.org/10.1107/s1600536809030165" @default.
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