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• W2070201393 abstract "The anodic behaviour of the ferrocenyl-derived compounds [Ph2PCH2C(O)(η5-C5H4) Fe(η-C5H5)] (1), [(o-C6H4CH2NMe2)PdPh2PCHC(O)(η5- C5H4)Fe(η5-C5H5)] (2) and [(o-C6H4CH2NMe2)Pd-ClPh2 PCH2C(O)(η5-C5H4)Fe(η5-C5H5)] (3) has been investigated in dichloromethane at a platinum electrode. Voltammetric and coulometric data, and spectral results, indicate that for each compound, the first electron loss corresponding to the oxidation of the ferrocenyl centre triggers an intramolecular electron transfer. In complexes 2 and 3, this results in the formation of transient radical cationic PdIII species whereas for 1 the electron transfer probably leads to a phosphonium cation radial." @default.
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• W2070201393 date "1992-10-01" @default.
• W2070201393 modified "2023-09-25" @default.
• W2070201393 title "Anodic oxidation of the ferrocenyl-derived β- ketophosphine [Ph2PCH2C(O)(η5-C5H4)Fe(η5-C5H5)] and of two of its p" @default.
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• W2070201393 doi "https://doi.org/10.1016/0022-328x(92)88015-b" @default.
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