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• W2070203397 startingPage "303" @default.
• W2070203397 abstract "This paper reports the synthesis, structure and the conductivity study of the new monovalent phosphates of the formula Na2MTi(PO4)3, M=Fe or Cr. The structures of these compounds have been refined from X-ray powder diffraction by the Rietveld method. Their reflections are indexed in the cubic system with langbeinite-type structure in the P213 space group. This structure can be best described in terms of [M2P3O18] structural units composed of two MO6 octahedra linked to each other through three PO4 tetrahedra. Curie-type behaviour is observed in the magnetic susceptibility, which confirms the trivalent state of M metals and suggest no magnetic interactions. The electrical behaviour of these phases show that the activation energies are relatively high and they could be related to the previous structural analysis" @default.
• W2070203397 created "2016-06-24" @default.
• W2070203397 creator A5001110326 @default.
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• W2070203397 date "2000-08-02" @default.
• W2070203397 modified "2023-10-02" @default.
• W2070203397 title "Synthesis, structure and conductivity study of new monovalent phosphates with the langbeinite structure" @default.
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• W2070203397 doi "https://doi.org/10.1016/s0167-2738(00)00677-9" @default.
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