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• W2070242488 abstract "Al 2 Si 2 O 5 (OH) 4 (halloysite) multiwalled nanotubes (MWNTs) were synthesized for the first time using a simple hydrothermal preparation technique involving the reaction SiO 2 + Al(OH) 3 in the presence of 0.1–0.2 mole fraction GeO 2 substituted for SiO2. The inclusion of small amounts of Ge(IV) into the Al 2 Si 2 O 5 (OH) 4 structure together with the creation of Si(IV) vacancies stimulates curving of layered nanosheets, such that they scroll to form spheroids, and finally tubes. At 0.5 GeO 2 substitution, small single-walled imogolite-type nanotubes (SWNTs) with the Al 2 Si x Ge 1−x O 3 (OH) 4 structure are formed instead alongside x-ray amorphous particles. Thus the substitution of GeO 2 for SiO 2 provides a direct method to control the morphology of nanostructured aluminosilicates." @default.
• W2070242488 created "2016-06-24" @default.
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• W2070242488 date "2012-08-01" @default.
• W2070242488 modified "2023-09-25" @default.
• W2070242488 title "Spontaneous scrolling of Al<inf>2</inf>Si<inf>2</inf>O<inf>5</inf>(OH)<inf>4</inf> nanosheets into halloysite nanotubes stimulated by structural doping with GeO<inf>2</inf>" @default.
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• W2070242488 doi "https://doi.org/10.1109/nano.2012.6321899" @default.
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