FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2070263369> ?p ?o ?g. }

• W2070263369 endingPage "855" @default.
• W2070263369 startingPage "843" @default.
• W2070263369 abstract "X-ray crystallography identifies the aromatic donor group D = 2,5-dimethoxy-4-methylphenyl to be a suitable redox center for the construction of organic mixed-valence crystals owing to its large structural change attendant upon 1e oxidation to the cation-radical (D*(+)). The combination of cyclic voltammetry, dynamic ESR line broadening, and electronic (NIR) spectroscopy allows the intervalence electron transfer between the redox centers in the mixed-valence system D-br-D*(+) [where br can be an aliphatic trimethylene or an aromatic (poly)phenylene bridge] to be probed quantitatively. Independent measures of the electronic coupling matrix element (H) for D/D*(+) electron exchange via Mulliken-Hush theory accord with the X-ray crystallographic data-both sufficient to consistently identify the various D-br-D*(+) according to the Robin-Day classification. Thus, the directly coupled biaryl D-D*(+) is a completely delocalized cation in class III with the charge distributed equally over both redox centers. The trimethylene- and biphenylene-bridged cations D(CH(2))(3)D*(+) and D(ph)(2)D*(+) with highly localized charge distributions are prototypical class II systems involving moderately coupled redox centers with H approximately equal to 400 cm(-1). The borderline region between class II/III is occupied by the phenylene-bridged cation D(ph)D*(+); and the X-ray, CV, and NIR analyses yield ambivalent H values (which we believe to be) largely a result of an unusually asymmetric (20/80) charge distribution that is polarized between the D/D*(+) redox centers." @default.
• W2070263369 created "2016-06-24" @default.
• W2070263369 creator A5030343286 @default.
• W2070263369 creator A5076181478 @default.
• W2070263369 creator A5080600554 @default.
• W2070263369 creator A5091859622 @default.
• W2070263369 date "2002-01-11" @default.
• W2070263369 modified "2023-10-16" @default.
• W2070263369 title "X-ray Structure Analysis and the Intervalent Electron Transfer in Organic Mixed-Valence Crystals with Bridged Aromatic Cation Radicals" @default.
• W2070263369 cites W1630368370 @default.
• W2070263369 cites W1691067281 @default.
• W2070263369 cites W1968355139 @default.
• W2070263369 cites W1969059256 @default.
• W2070263369 cites W1971944253 @default.
• W2070263369 cites W1975402322 @default.
• W2070263369 cites W1976678711 @default.
• W2070263369 cites W1987261113 @default.
• W2070263369 cites W1993439357 @default.
• W2070263369 cites W1994773831 @default.
• W2070263369 cites W1995180741 @default.
• W2070263369 cites W2001277223 @default.
• W2070263369 cites W2001948045 @default.
• W2070263369 cites W2003653856 @default.
• W2070263369 cites W2005744965 @default.
• W2070263369 cites W2005819782 @default.
• W2070263369 cites W2007679907 @default.
• W2070263369 cites W2008631597 @default.
• W2070263369 cites W2010747249 @default.
• W2070263369 cites W2014394792 @default.
• W2070263369 cites W2016592851 @default.
• W2070263369 cites W2018201939 @default.
• W2070263369 cites W2022150513 @default.
• W2070263369 cites W2022600348 @default.
• W2070263369 cites W2023665942 @default.
• W2070263369 cites W2030037054 @default.
• W2070263369 cites W2030572740 @default.
• W2070263369 cites W2032587009 @default.
• W2070263369 cites W2032657118 @default.
• W2070263369 cites W2037878224 @default.
• W2070263369 cites W2040369468 @default.
• W2070263369 cites W2044931258 @default.
• W2070263369 cites W2046133238 @default.
• W2070263369 cites W2050299142 @default.
• W2070263369 cites W2050929277 @default.
• W2070263369 cites W2051338268 @default.
• W2070263369 cites W2057820608 @default.
• W2070263369 cites W2071277211 @default.
• W2070263369 cites W2077934512 @default.
• W2070263369 cites W2079507386 @default.
• W2070263369 cites W2088310002 @default.
• W2070263369 cites W2090374169 @default.
• W2070263369 cites W2094820352 @default.
• W2070263369 cites W2144087168 @default.
• W2070263369 cites W2148114718 @default.
• W2070263369 cites W2158046987 @default.
• W2070263369 cites W2497007159 @default.
• W2070263369 cites W2949338118 @default.
• W2070263369 cites W2952407772 @default.
• W2070263369 cites W78659184 @default.
• W2070263369 doi "https://doi.org/10.1021/ja011579j" @default.
• W2070263369 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11817960" @default.
• W2070263369 hasPublicationYear "2002" @default.
• W2070263369 type Work @default.
• W2070263369 sameAs 2070263369 @default.
• W2070263369 citedByCount "105" @default.
• W2070263369 countsByYear W20702633692012 @default.
• W2070263369 countsByYear W20702633692013 @default.
• W2070263369 countsByYear W20702633692014 @default.
• W2070263369 countsByYear W20702633692015 @default.
• W2070263369 countsByYear W20702633692016 @default.
• W2070263369 countsByYear W20702633692017 @default.
• W2070263369 countsByYear W20702633692018 @default.
• W2070263369 countsByYear W20702633692019 @default.
• W2070263369 countsByYear W20702633692020 @default.
• W2070263369 countsByYear W20702633692021 @default.
• W2070263369 countsByYear W20702633692022 @default.
• W2070263369 countsByYear W20702633692023 @default.
• W2070263369 crossrefType "journal-article" @default.
• W2070263369 hasAuthorship W2070263369A5030343286 @default.
• W2070263369 hasAuthorship W2070263369A5076181478 @default.
• W2070263369 hasAuthorship W2070263369A5080600554 @default.
• W2070263369 hasAuthorship W2070263369A5091859622 @default.
• W2070263369 hasBestOaLocation W20702633692 @default.
• W2070263369 hasConcept C123669783 @default.
• W2070263369 hasConcept C139066938 @default.
• W2070263369 hasConcept C145148216 @default.
• W2070263369 hasConcept C147789679 @default.
• W2070263369 hasConcept C168900304 @default.
• W2070263369 hasConcept C17525397 @default.
• W2070263369 hasConcept C178790620 @default.
• W2070263369 hasConcept C179104552 @default.
• W2070263369 hasConcept C185592680 @default.
• W2070263369 hasConcept C2777869211 @default.
• W2070263369 hasConcept C52859227 @default.
• W2070263369 hasConcept C55904794 @default.
• W2070263369 hasConcept C70050531 @default.
• W2070263369 hasConcept C75473681 @default.
• W2070263369 hasConcept C8010536 @default.

• next