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- W2070266368 abstract "Abstract Cyclopentadiene nitroso adducts 1a and ent - 1a were synthesised in good yields and good enantiomeric excess from chiral chloro-nitroso derivatives 4 and 5 in the d -mannose and d -ribose series, respectively. The thermal racemisation of these adducts occurred below room temperature. Some other chiral Diels–Alder nitroso adducts were prepared in the d -mandelic, l -prolinol and d - O -methylprolinol series and their thermal isomerisation was specified according to the N-substitution. A simple synthesis of the chiral amido-cyclopentenol (+)- 2b , an important precursor for biological interesting compounds, is presented from ent - 1a ." @default.
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- W2070266368 date "2012-11-01" @default.
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- W2070266368 title "Chiral Diels–Alder reaction between cyclopentadiene and nitroso derivatives: thermal isomerisation/racemisation of the adducts" @default.
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- W2070266368 doi "https://doi.org/10.1016/j.tetasy.2012.09.005" @default.
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